Graphene oxide-mediated rapid dechlorination of carbon tetrachloride by green rust

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Standard

Graphene oxide-mediated rapid dechlorination of carbon tetrachloride by green rust. / Huang, Lizhi; Hansen, Hans Chr. Bruun; Daasbjerg, Kim.

I: Journal of Hazardous Materials, Bind 323, Nr. Part B, 2017, s. 690-697.

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt

Harvard

Huang, L, Hansen, HCB & Daasbjerg, K 2017, 'Graphene oxide-mediated rapid dechlorination of carbon tetrachloride by green rust', Journal of Hazardous Materials, bind 323, nr. Part B, s. 690-697. https://doi.org/10.1016/j.jhazmat.2016.10.038

APA

Huang, L., Hansen, H. C. B., & Daasbjerg, K. (2017). Graphene oxide-mediated rapid dechlorination of carbon tetrachloride by green rust. Journal of Hazardous Materials, 323(Part B), 690-697. https://doi.org/10.1016/j.jhazmat.2016.10.038

Vancouver

Huang L, Hansen HCB, Daasbjerg K. Graphene oxide-mediated rapid dechlorination of carbon tetrachloride by green rust. Journal of Hazardous Materials. 2017;323(Part B):690-697. https://doi.org/10.1016/j.jhazmat.2016.10.038

Author

Huang, Lizhi ; Hansen, Hans Chr. Bruun ; Daasbjerg, Kim. / Graphene oxide-mediated rapid dechlorination of carbon tetrachloride by green rust. I: Journal of Hazardous Materials. 2017 ; Bind 323, Nr. Part B. s. 690-697.

Bibtex

@article{e3f341a30e9d4affa4acf1057ed1ef77,
title = "Graphene oxide-mediated rapid dechlorination of carbon tetrachloride by green rust",
abstract = "Graphene-based nanomaterials can mediate environmentally relevant abiotic redox reactions of chlorinated aliphatic hydrocarbons. In this study as low amounts as ∼0.007 % of graphene oxide (GO) was found to catalyze the reduction of carbon tetrachloride by layered Fe(II)-Fe(III) hydroxide (Green Rust, GR) in aqueous solutions with chloroform being the reduction product. On the basis of sorption studies of carbon tetrachloride onto the GO surface it is suggested that it is the amphiphilicity of GO, which initiates the reaction by providing a suitable reaction platform for the reagents. This study indicates that traces of graphene oxide can affect reaction pathways as well as kinetics for dechlorination processes in anoxic sediments by facilitating a partial dechlorination.",
author = "Lizhi Huang and Hansen, {Hans Chr. Bruun} and Kim Daasbjerg",
note = "Copyright {\textcopyright} 2016. Published by Elsevier B.V.",
year = "2017",
doi = "10.1016/j.jhazmat.2016.10.038",
language = "English",
volume = "323",
pages = "690--697",
journal = "Journal of Hazardous Materials",
issn = "0304-3894",
publisher = "Elsevier",
number = "Part B",

}

RIS

TY - JOUR

T1 - Graphene oxide-mediated rapid dechlorination of carbon tetrachloride by green rust

AU - Huang, Lizhi

AU - Hansen, Hans Chr. Bruun

AU - Daasbjerg, Kim

N1 - Copyright © 2016. Published by Elsevier B.V.

PY - 2017

Y1 - 2017

N2 - Graphene-based nanomaterials can mediate environmentally relevant abiotic redox reactions of chlorinated aliphatic hydrocarbons. In this study as low amounts as ∼0.007 % of graphene oxide (GO) was found to catalyze the reduction of carbon tetrachloride by layered Fe(II)-Fe(III) hydroxide (Green Rust, GR) in aqueous solutions with chloroform being the reduction product. On the basis of sorption studies of carbon tetrachloride onto the GO surface it is suggested that it is the amphiphilicity of GO, which initiates the reaction by providing a suitable reaction platform for the reagents. This study indicates that traces of graphene oxide can affect reaction pathways as well as kinetics for dechlorination processes in anoxic sediments by facilitating a partial dechlorination.

AB - Graphene-based nanomaterials can mediate environmentally relevant abiotic redox reactions of chlorinated aliphatic hydrocarbons. In this study as low amounts as ∼0.007 % of graphene oxide (GO) was found to catalyze the reduction of carbon tetrachloride by layered Fe(II)-Fe(III) hydroxide (Green Rust, GR) in aqueous solutions with chloroform being the reduction product. On the basis of sorption studies of carbon tetrachloride onto the GO surface it is suggested that it is the amphiphilicity of GO, which initiates the reaction by providing a suitable reaction platform for the reagents. This study indicates that traces of graphene oxide can affect reaction pathways as well as kinetics for dechlorination processes in anoxic sediments by facilitating a partial dechlorination.

U2 - 10.1016/j.jhazmat.2016.10.038

DO - 10.1016/j.jhazmat.2016.10.038

M3 - Journal article

C2 - 27776856

VL - 323

SP - 690

EP - 697

JO - Journal of Hazardous Materials

JF - Journal of Hazardous Materials

SN - 0304-3894

IS - Part B

ER -

ID: 168884096