Bulk and compound-specific stable isotope ratio analysis for authenticity testing of organically grown tomatoes
Research output: Contribution to journal › Journal article › Research › peer-review
Standard
Bulk and compound-specific stable isotope ratio analysis for authenticity testing of organically grown tomatoes. / Bontempo, Luana; van Leeuwen, Katryna A.; Paolini, Mauro; Laursen, Kristian Holst; Micheloni, Cristina; Prenzler, Paul D.; Ryan, Danielle; Camin, Federica.
In: Food Chemistry, Vol. 318, 126426, 2020.Research output: Contribution to journal › Journal article › Research › peer-review
Harvard
APA
Vancouver
Author
Bibtex
}
RIS
TY - JOUR
T1 - Bulk and compound-specific stable isotope ratio analysis for authenticity testing of organically grown tomatoes
AU - Bontempo, Luana
AU - van Leeuwen, Katryna A.
AU - Paolini, Mauro
AU - Laursen, Kristian Holst
AU - Micheloni, Cristina
AU - Prenzler, Paul D.
AU - Ryan, Danielle
AU - Camin, Federica
PY - 2020
Y1 - 2020
N2 - Until now, there has been a lack of analytical methods that can reliably verify the authenticity of organically grown plants and derived organic food products. In this study, stable isotope ratio analysis of hydrogen (H, δ2H), carbon (C, δ13C), nitrogen (N, δ15N), oxygen (O, δ18O) and sulfur (S, δ34S) was conducted along the tomato passata production process using organic and conventionally grown tomatoes from two Italian regions over two years. A gas chromatography-combustion-isotope ratio mass spectrometry (GC-C-IRMS) based method was developed and applied for analysis of C and N isotope ratios in amino acids derived from tomatoes. Of the bulk isotope ratios, δ15N was the most significant parameter for discriminating organic from conventional products. The classification power was improved significantly by compound-specific isotope analysis regardless of the production years and regions. We conclude that isotope analysis of amino acids is a novel analytical tool for complementing existing certification and control procedures in the organic tomato sector.
AB - Until now, there has been a lack of analytical methods that can reliably verify the authenticity of organically grown plants and derived organic food products. In this study, stable isotope ratio analysis of hydrogen (H, δ2H), carbon (C, δ13C), nitrogen (N, δ15N), oxygen (O, δ18O) and sulfur (S, δ34S) was conducted along the tomato passata production process using organic and conventionally grown tomatoes from two Italian regions over two years. A gas chromatography-combustion-isotope ratio mass spectrometry (GC-C-IRMS) based method was developed and applied for analysis of C and N isotope ratios in amino acids derived from tomatoes. Of the bulk isotope ratios, δ15N was the most significant parameter for discriminating organic from conventional products. The classification power was improved significantly by compound-specific isotope analysis regardless of the production years and regions. We conclude that isotope analysis of amino acids is a novel analytical tool for complementing existing certification and control procedures in the organic tomato sector.
KW - Amino acids
KW - Compound-specific
KW - Organic
KW - Stable isotope ratios
KW - Tomatoes
U2 - 10.1016/j.foodchem.2020.126426
DO - 10.1016/j.foodchem.2020.126426
M3 - Journal article
C2 - 32135420
AN - SCOPUS:85080097339
VL - 318
JO - Food Chemistry
JF - Food Chemistry
SN - 0308-8146
M1 - 126426
ER -
ID: 238678103